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LiFePO₄ (lithium iron phosphate) batteries are generally known for their stability, long cycle life, and safety compared to other lithium-ion chemistries. LiFePO₄ batteries can be discharged at sub-zero temperatures, though at a reduced efficiency. They lose capacity more quickly in cold weather, meaning they won’t deliver as much energy per charge. Charging at temperatures below 0°C can lead to lithium plating on the anode, which can permanently damage the battery. For this reason, most manufacturers recommend not charging below freezing unless the battery is specifically designed with internal heating mechanisms.

Some lifepo4 battery 12v 200ah price systems include built-in heaters to allow safer operation in colder environments. Pre-heating the battery before charging or using external heating enclosures are also common solutions. LiFePO₄ batteries can generally handle higher temperatures better than other lithium-ion types, with typical operating temperature limits up to around 60°C (140°F). However, prolonged exposure to high temperatures can still lead to capacity degradation over time, and charging at very high temperatures can damage the battery.

Compared to other lithium-ion chemistries, LiFePO₄ is more resistant to thermal runaway, meaning it is less likely to overheat and catch fire in high-temperature environments. For optimal performance and longevity, LiFePO₄ batteries are best used and charged between 0°C and 40°C (32°F to 104°F). Cold temperatures reduce capacity, and high temperatures can shorten lifespan over time. A good BMS can help protect the battery in extreme temperatures by regulating charging and discharging parameters.